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Science

Scientists make plastic from carbon dioxide and sugar

Researchers from the University of Bath in the United Kingdom have created biodegradable plastic that could one day replace oil-based plastics, which take centuries to break down.

Conventional plastic takes centuries to break down, this one takes just weeks

Researchers from the University of Bath, U.K., are hoping the biodegradable plastic they've created from CO2 and sugar will one day help cut down on use of synthetic plastics that end up in landfills. (Shutterstock/Gigira)

Imagine a world without landfills and water systems clogged with plastic waste.

Researchers from the University of Bath in the United Kingdom have moved a step closer in trying to make that a reality, by creating plastic out of carbon dioxide (CO2) and sugar natural sources that can takeweeks to break down,instead of the hundreds of years it takes for today's common synthetic plastics to degrade.

AntoineBuchard, co-author of astudythatappearsin the journal Polymer Chemistry, says scientists play a key role in finding better ways to dispose of materials that can harm the environment. Work by Buchard and his colleagues augmentsother studiesthat have also focusedon creating greener plastics.

"It's our job as scientists to address this type of problem,"Buchardtold CBC."We need to have science and technology to sustain our modern way of living."

Used to make everything frombottles to computer keyboards andclothing, plastic oftenends up in landfills andoceans and other bodies of water, and can take450 years to break down. The first plasticinvented in 1907 could still be around for 340 years.
This graphic from University of Bath researchers shows part of their work in turning carbon dioxide and sugar into biodegradable plastic. (Georgina Gregory)

That's because plastic is madefrom polymerschemical compounds with molecules bound together in repeating chains that are tough to break down.

Polyethyleneterephthalate(PET)is one of the most common forms of plastic, found in items including water bottles, containers, ropes and combs.

As part of the Bath scientists' research, they collectedsugar, combined it in a solution with carbon dioxide at low pressure and an ambient temperature. They then added certain chemicals to bind the CO2 with the sugar.

"What you get at the end is a monomer [a type of molecule], the monomer being the building block that's going to make the polymer,"Buchardsaid. "Basically we've done two things: we've developed a method that makes this building block, but we've also shown that this building block, this monomer, we canpolymerizeit and transfer it into a plastic."

This biodegradable plasticcreated by the Bath researchers breaks down in water with basic properties(not the type we drink which is neutral)leaving thecarbon dioxide and sugar used to make it in the first place.

The researchers hope that one day theresulting organic wastecan be recollected to be used again to make more plastic, minimizing the carbon footprint.

Challenges ahead

The researchers stress that more work needs to be done before the plasticthey created isas durable and cost effective as today's standard syntheticplastics, making it more likely to be accepted by manufacturers for use in everyday items.

"We are at this stage that we've developed the process to make the material," saidBuchard. "What we're looking at right now is, make more of it, testit mechanically, look at durability, toughness to impact."

Mountains of plastic on Thilafushi Island in the Maldives. The artificial island was created to deal with municipal waste. (Shutterstock/Mohamed Abdulraheem)

More research also needs to go into the type of compounds they used in their work.

For instance, tosylchoride is anorganic compound that's commonly used in laboratories and is relatively inexpensive, but it's not perfect because it's afossil fuel resource that countries are trying to move away from for environmental reasons.